James C. Keck publications and biography  

(1924-2010)

 

Biographical Notes

 

Main Scientific Publications

 

Other Scientific Publications

 

Photo Gallery

 

 

 

 

Biographical Notes

 

The following biographical notes are taken from R.F. Probstein, Memorial Tributes: National Academy of Engineering, Vol.15, 237 (2010).  James Keck was elected to the National Academy of Engineering in 2002 “For developing innovative, widely used new concepts for modeling coupled chemical and physical phenomena in engine combustion and high-temperature flows.

 

Jim was born in New York City on June 11, 1924, the son of famed sculptor Charles Keck. He spent his early years in Greenwich Village, where his father’s studio was located, but financial losses resulting from the Great Depression forced the family to leave Manhattan and move to their country home in Carmel, New York.

He graduated from Carmel High School in 1942 and then went to Cornell University where he majored in physics and minored in mathematics. An outstanding student in physics, in 1944 he was drafted into the Special Engineering Detachment of the U.S. Army, given the rank of technical sergeant, and sent to Los Alamos to work on the atomic bomb project as part of the Manhattan Project. Years later Jim told me, “I can’t understand how they picked me because I was just a kid and hadn’t been at Cornell that long to know enough physics to be useful.” I never had any doubt that was a usual understatement by Jim who was an outstanding student. This was confirmed to me some years afterwards by his supervisors at Cornell, Hans Bethe, who in 1943 became director of the Theoretical Division of the Manhattan project at Los Alamos and later won the Nobel Prize for his contributions to the theory of nuclear reactions, and mathematics professor Mark Kac, who was the developer of modern mathematical probability theory and its applications to statistical physics.

Jim left Los Alamos in 1946 and returned to Cornell to complete his studies in nuclear physics, receiving his B.S. in 1947 and his Ph.D. in 1951. Among his many life-changing events at Los Alamos was his meeting another physicist, Margaret Ramsey, one of the few women scientists employed on the Manhattan Project, which she joined in 1945. She also left the project in 1946 and went to Indiana University to pursue a master’s degree, which she completed while working in physics at Cornell. She and Jim were married in 1947. They both were employed in the physics department at Cornell through 1952, where Jim conducted pioneering experimental investigations of photo-nuclear reactions on a 300-Mev synchrotron he assisted in developing. He then went to the California Institute of Technology for three years as a senior research fellow, where he continued his studies of photonuclear reactions on the 500-Mev Caltech synchrotron.

In 1955, at the height of the Cold War, Arthur Kantrowitz, a professor at Cornell, had become convinced that the most important problem facing America was the need to develop intercontinental ballistic missiles (ICBMs). He foresaw Russia’s threatening missile development, which was confirmed dramatically two years later with the launching of the Sputnik satellite. To counteract the Russian program, he decided to set up a research laboratory in Everett, Massachusetts, under the umbrella of the Avco Corporation for the purpose of providing the research needed to develop ICBMs that could reenter the atmosphere without burning up. He had not known Jim from Cornell but had heard from Victor Emanuel the head of Avco that Jim was brilliant, a fact passed on to him by his son who did know Jim. Kantrowitz very much wanted Jim and in 1955, at a time when Jim was prepared to go to Princeton, convinced him, along with a number of other Cornell alumni, to join the new Avco-Everett Research Laboratory to help protect America from Russian domination in ICBM development. Jim started at the Avco-Everett Laboratory as a principal scientist, where he carried out both experimental and theoretical studies of the chemical kinetics, radiation, and ionization of gases heated by high-intensity shock waves. Such shock waves are associated with the very high Mach number speeds of reentry of ICBMs. He also had general responsibility for the laboratory’s associated programs in atomic physics. His experimental and theoretical contributions in the areas of nonequilibrium rate processes and the radiation of neutral gases and plasmas obtained wide recognition. His pioneering work on the variational theory of reaction rates laid a foundation for the theoretical description of thermally induced gas-phase reactions, which received wide acclaim in the field of physical chemistry.

In 1960, Jim was appointed deputy director of the laboratory but resigned that position in 1963. He had told me “the responsibilities of running the Lab aren’t compatible with my doing my own creative research and that’s what I want to do.” I was a consultant to the laboratory at the time, and it was clear that his brilliance, coupled with his devotion to try to understand scientific and engineering problems at their basic level, made him far more suited to a university environment than to an industrial laboratory. With little effort I convinced my colleagues at the Massachusetts Institute of Technology that we should invite him to join us, and in 1965 Jim accepted the position of Ford Professor of Engineering in the Department of Mechanical Engineering at MIT.

Shortly after joining the MIT faculty Jim assumed primary responsibility for the direction and teaching of thermodynamics in the mechanical engineering department. He emphasized the important, but less well understood, nonequilibrium aspects of the subject, processes in the gas-phase, gas-surface interactions, thermionic energy conversion, and air pollution problems associated with combustion.

As a consequence of his experimental and theoretical research into the combustion processes occurring in spark ignition engines, he obtained a much clearer understanding of automotive pollution problems insofar as the production of nitric oxide, carbon monoxide, and unburned hydrocarbons are concerned. He also showed the nature of turbulent flame propagation and “knock” in these engines. Taken together his work identified methods by which these pollutants could be alleviated. These studies are regarded as a pioneering contribution to the design of all present-day efficient and clean automobile internal combustion engines.

Until his death Jim worked to develop basic theoretical models to describe elementary atomic and molecular excitation, thermally induced chemical reaction rates, rate-controlled constrained equilibrium, and flame theory, in addition to continuing to understand the nature of engine combustion. He produced outstanding research right up to his last days. As for his personal happiness, there never was a question for he was a happy fellow who found joy in both his work and his friends at the institute and who was loved by them all. In my many years as a friend of Jim, I never heard anyone say anything about him less than “What a nice fellow. “ He devoted himself to his students and was never patronizing to them or his colleagues but rather was always ready to jump into their technical problems because it was fun. He loved science and was forever curious, and it was difficult for him not to start talking to his colleagues without getting involved in their problems or raising issues with his own work because it was fun.

As involved as he was with engineering and science he had a lifelong attachment to his extracurricular activities, among which was his vegetable garden at his home in Harold Parker State Forest in Andover, Massachusetts. This was a serious matter and not on a small scale. Indeed, it required the use of a backhoe, which Jim acquired and used in a way admired by professionals. But no matter what the task, always at the forefront of Jim’s behavior were fun and games. As he once expressed to me, “I would rather be loved than famous.” He didn’t quite get his wish, for not only was he loved by all but was also recognized and honored internationally for his pioneering scientific and engineering studies.

While gardening was a major hobby, Jim also enjoyed individual sports. In the winter it was ice skating and skiing; in the warmer months it was swimming or hiking or bicycling. When his children were growing up, he spent much of his free time with them, encouraging them to pursue their interests, and he was always willing to help them, whether it was building a dark room for his son’s photography or putting up fences for his daughter’s horse. In later years Jim enjoyed working with his daughter Pat, a sculptor, on the mechanical design of her movable sculptures, teaching her basic mechanics in the process and emphasizing that the simplest design was usually the best. He liked to say, “If you can’t explain something simply, you probably don’t understand it very well.” That was a concept he used in approaching any problem.

Jim enjoyed parties and celebrations and threw himself into the preparations with great enthusiasm. He hosted many parties for graduate students and faculty, with the entertainment as varied as ice skating and sledding to badminton and swimming. He was popular with visiting children because he was always willing to stop whatever he was doing to play games with them or have a croquet match, set up an archery range, or teach them new skills. Adults, meanwhile, enjoyed his talents in mixing martinis. Jim was an optimist and was invariably cheerful and upbeat. He was a joy to live with, and he brought joy to all who knew him.

When he retired from MIT in 1989, he took on some new ventures. First, he designed and built, with the help of his daughter, a two-car garage to replace the one that she had taken over for use as her studio. This was top priority for his wife, who was tired of scraping ice off the cars during the long New England winters. Second, he designed and, again with Pat as helper, built a barn to house two horses and a storage area for garden machinery. From then on, one of his main occupations was improving and maintaining his house and property. He loved the hard physical outdoor work that this entailed, but he also claimed that he got some of his best scientific ideas while mowing the fields with his garden tractor. In the 1990s, as a result of a chance conversation with a friend, he invented and worked on the development of a device to monitor septic systems that led to the formation of a company now known as Sepsensor, Inc. He never lost his interest in thermodynamics and continued to work until the end of his life on nonequilibrium thermodynamics and rate-controlled constrained equilibrium, meeting weekly with Northeastern University doctoral students who were interested in pursuing his ideas.

In addition to the honor of his election to the National Academy of Engineering, he was honored by election to the American Academy of Arts and Sciences and was a fellow of the American Physical Society.

 

The following was taken from MIT News on August 13, 2010.

 

James C. Keck, was professor emeritus in the Department of Mechanical Engineering when he died on Aug. 9, 2010. He was 86.

Keck joined MIT in 1965 as the Ford Professor of Engineering and developed teaching and research programs in thermodynamics, kinetics and mechanics related to energy generation and air pollution. Keck was the author of dozens of papers, and his research at MIT focused on atomic and molecular kinetics, thermodynamics and high-temperature gas dynamics. He was recognized by the National Academy of Engineering for “developing innovative, widely used concepts for modeling coupled chemical and physical phenomena in engine combustion and high-temperature flow.”

“Few of Professor Keck’s students and colleagues will ever forget seeing him walking around MIT with a sharp pencil and a pad of paper filled with equations and diagrams, ready to engage us in deep technical conversations filled with sharp intuition and insight few others possess,” said Ahmed Ghoniem, Ronald C. Crane professor in the Department of Mechanical Engineering and a colleague of Keck’s for 27 years. “His child-like enthusiasm for science and engineering was contagious and led to significant and long-lasting contributions in engine development and energy sciences. Jim always maintained that complex systems are governed by few parameters and that their behavior can be quantified accurately using ‘simplified’ models built around the Second Law of Thermodynamics. He always asked, ‘What is your model?’ insisting that conceptualization is the essence of engineering science.”

Keck was born in New York City in 1924. In 1944, when he was studying physics at Cornell University, he was put into the U.S. Army Special Engineering Detachment and sent to Los Alamos to work on the atomic bomb. There he met Margaret Ramsey, who was also working at Los Alamos as a physicist: the two would marry in 1947.

After the war, Keck returned to Cornell, where he received a BA in 1947 and a PhD in 1951. His early interests included high-energy particle physics: Keck carried out pioneering research in photo-nuclear reactions and in spectral radiation from high-temperature shock-heated air.

In 1952, after serving as a research associate at Cornell, Keck left for the California Institute of Technology, where he served as a research fellow until 1955. That year, he joined the Avco Everett Research Laboratory, where he researched the reentry of missiles and spacecraft into the atmosphere. At the time of his departure from AERL in 1965, he served as its deputy director.

After joining the MIT faculty in 1965, he began researching the problem of burning rates and pollutant formation in internal combustion engines. His experiments and theoretical studies showed many things about such engines: how nitric oxide is formed in them, the nature of turbulent flame propagation, and the nature of “knock.” His work is widely used in the automotive industry in the design of efficient and clean engines.

After retiring from MIT, Keck advised graduate students at Northeastern University.

Until his death, Keck worked to develop basic theoretical models to describe elementary atomic and molecular excitation, thermally induced chemical-reaction rates, rate-controlled constrained-equilibrium, flame theory and engine combustion.

Ronald Probstein, Ford Professor of Engineering, Emeritus, was responsible for getting Keck to come to MIT. Probstein met Keck in 1955 at AERL, where Probstein was a consultant. The two remained close friends until Keck’s death. “Jim was a remarkable person, having continued to produce outstanding research right up to his last days,” Probstein said. “Despite his outpouring of work throughout his life, which made him an outstanding scientist esteemed throughout the scientific world, I always remember a remark he once made to me, that ‘I'd rather be loved than famous.’”

Keck was a member of the National Academy of Engineering, the American Academy of Arts and Sciences, and the American Physical Society.