NOTE: If in your computer or smartphone the "Slide" hyperlinks take you to slide 1 instead of the target slide, you may have to change your default settings. For example:

• In PC Chrome: Settings -> Privacy and Security -> Site Settings -> PDF documents, and choose to open PDFs in Chrome.

• In PC Firefox: Preferences -> General -> Applications -> Portable Document Format (PDF), and select “Open in Firefox".

• In some Android smartphones, download the Firefox app, then: Settings -> Applications -> Firefox -> “Set as Default", and choose Firefox.

Table of Contents of Lecture 9

• Slide 09.01: Welcome - Slide - Video timestamp

• Slide 09.02: Results So Far Hold for Large and Small Systems - Slide - Video timestamp

• Slide 09.03: Review: Microscopic and Mesoscopic vs Macroscopic - Slide - Video timestamp

• Slide 09.04: Review: Rarefaction Effects Near Walls - Slide - Video timestamp

• Slide 09.05: Review: Neglecting Effects of Partitions - Slide - Video timestamp

• Slide 09.06: Review: Simple-System Model Limiting Assumptions - Slide - Video timestamp

• Slide 09.07: Review: Simple-System Model Implies Euler Relation - Slide - Video timestamp

• Slide 09.08: Review: Main Consequence of Euler Relation - Slide - Video timestamp

• Slide 09.09: Small Systems: Specific Properties Dependences - Slide - Video timestamp

• Slide 09.10: Small Systems: Minimum Work of Partitioning - Slide - Video timestamp

• Slide 09.12: Basic Simple-System Models for Pure Substances - Slide - Video timestamp

• Slide 09.13: Extensive Properties (Definition) - Slide - Video timestamp

• Slide 09.14: Specific Properties (Definition) - Slide - Video timestamp

• Slide 09.15: Intensive Properties and Intensive State - Slide - Video timestamp

• Slide 09.16: Homogeneous vs Heterogeneous States; Phases - Slide - Video timestamp

• Slide 09.17: Gibbs Phase Rule (Proof) - Slide - Video timestamp

• Slide 09.18: Gibbs Phase Rule (for a Pure Substance) - Slide - Video timestamp

• Slide 09.20: Fundamental Relation for a Pure Substance - Slide - Video timestamp

• Slide 09.21: Ideal Incompressible Solid or Fluid Model - Slide - Video timestamp

• Slide 09.22: Ideal Gas Model - Slide - Video timestamp

• Slide 09.24: Two-Phase States of a Pure Substance - Slide - Video timestamp

• Slide 09.25: Properties Liquid-Vapor States of a Pure Substance - Slide - Video timestamp

• Slide 09.26: Graphical Representation of Fundamental Relation - Slide - Video timestamp

• Slide 09.27: The u-s-v Fundamental Surface (Water) - Slide - Video timestamp

• Slide 09.28: The Mollier h-s Diagram (Water) - Slide - Video timestamp

• Slide 09.29: The p-v Diagram (Water) - Slide - Video timestamp

• Slide 09.30: The p-v Diagram (Van der Waals Model) - Slide - Video timestamp

• Slide 09.31: Exergies and Efficiencies in Energy Conversion - Slide - Video timestamp

• Slide 09.32: Exergy and Second-Law Efficiency in Cogeneration - Slide - Video timestamp

• Slide 09.33: Exergy of Bulk Flow Interactions - Slide - Video timestamp

FAQs for Lecture 09

Analytical Index of Lecture 9 Contents

• Clausius-Clapeyron relation - Slide - Video timestamp

• Energy-entropy-volume diagram for water - Slide - Video timestamp

• Euler free energy and minimum work of partitioning a small system - Slide - Video timestamp

• Euler free energy and properties of small systems - Slide - Video timestamp

• Euler free energy how to measure it for small systems - Slide - Video timestamp

• Euler free energy how to measure it for small systems - Slide - Video timestamp

• Euler free energy physical interpretation - Slide - Video timestamp

• Euler relation proof - Slide - Video timestamp

• Exergy and second-law efficiency - Slide - Video timestamp

• Exergy transfer in a bulk-flow interaction - Slide - Video timestamp

• Extensive property - Slide - Video timestamp

• Fundamental relation fundamental $u$-$s$-$v$ surface - Slide - Video timestamp

• Fundamental relation of a pure substance - Slide - Video timestamp

• Gibbs phase rule - Slide - Video timestamp

• Gibbs relation general - Slide - Video timestamp

• Gibbs-Duhem relation for a pure substance - Slide - Video timestamp

• Gibbs-Duhem relation general - Slide - Video timestamp

• Ideal gas behavior - Slide - Video timestamp

• Ideal gas model - Slide - Video timestamp

• Ideal incompressible behavior - Slide - Video timestamp

• Ideal incompressible fluid model - Slide - Video timestamp

• Ideal incompressible solid model - Slide - Video timestamp

• Intensive property - Slide - Video timestamp

• Intensive state - Slide - Video timestamp

• Liquid-vapor equilibrium - Slide - Video timestamp

• Liquid-vapor equilibrium - Slide - Video timestamp

• Macroscopic limit simple-system model - Slide - Video timestamp

• Macroscopic limit simple-system model - Slide - Video timestamp

• Many-particle limit simple-system model - Slide - Video timestamp

• Many-particle limit simple-system model - Slide - Video timestamp

• Minimum work of partitioning a small system - Slide - Video timestamp

• Mollier $h$-$s$ diagram for water - Slide - Video timestamp

• Partitioning small systems Euler free energy - Slide - Video timestamp

• Partitioning small systems minimum work - Slide - Video timestamp

• Perfect gas behavior - Slide - Video timestamp

• Perfect gas model - Slide - Video timestamp

• Perfect incompressible behavior - Slide - Video timestamp

• Perfect incompressible fluid model - Slide - Video timestamp

• Perfect incompressible solid model - Slide - Video timestamp

• Phase definition - Slide - Video timestamp

• Phase Gibbs rule - Slide - Video timestamp

• Pressure-volume diagram for a van der Waals fluid - Slide - Video timestamp

• Pressure-volume diagram for water - Slide - Video timestamp

• Property extensive - Slide - Video timestamp

• Property intensive - Slide - Video timestamp

• Property specific - Slide - Video timestamp

• Pure substance properties of homogeneous SES's - Slide - Video timestamp

• Pure substance properties of ideal gas SES's - Slide - Video timestamp

• Pure substance properties of ideal incompressible SES's - Slide - Video timestamp

• Pure substance properties of two-phase SES's - Slide - Video timestamp

• Second-law efficiency in heating and cooling of bulk flows - Slide - Video timestamp

• Simple-system model effect of inserting and removing partitions - Slide - Video timestamp

• Simple-system model rarefaction effects near walls - Slide - Video timestamp

• Small systems and Euler free energy - Slide - Video timestamp

• Small systems minimum work of partitioning - Slide - Video timestamp

• Small systems SES properties depend on $n$ - Slide - Video timestamp

• Small systems simple-system model (large $n$ limit) - Slide - Video timestamp

• Small systems vs large $n$ limit - Slide - Video timestamp

• Specific heat for an incompressible substance - Slide - Video timestamp

• Specific heats and degrees of freedom for ideal gases - Slide - Video timestamp

• Specific property - Slide - Video timestamp

• Stable equilibrium state heterogeneous - Slide - Video timestamp

• Stable equilibrium state homogeneous - Slide - Video timestamp

• Stable equilibrium state properties depend on $n$, for small systems - Slide - Video timestamp

• System SES properties for small $n$ - Slide - Video timestamp

• System SES properties for small $n$ - Slide - Video timestamp

• System small vs large $n$ limit - Slide - Video timestamp

• Van der Waals p-v diagram - Slide - Video timestamp

• Van der Waals model for a pure substance - Slide - Video timestamp

Back to the main course index page to see more lectures and direct links to the 2.43 MIT-OCW webpages.

See the Complete Analytical Index of the Course with Hyperlinks to All Videos and Slides.