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Table of Contents of Lecture 6

• Slide 06.01: Welcome - Slide - Video timestamp

• Slide 06.02: Review: Definition of Heat Interaction - Slide - Video timestamp

• Slide 06.03: Energy Exchange Entirely Distinguishable from Work - Slide - Video timestamp

• Slide 06.04: Steady State Heat Transfer Requires Nonequilibrium - Slide - Video timestamp

• Slide 06.05: Temperature as Escaping Tendency for Energy - Slide - Video timestamp

• Slide 06.06: Chemical Potential as Escaping Tendency for Matter - Slide - Video timestamp

• Slide 06.07: Measurement of Stable-Equilibrium Properties - Slide - Video timestamp

• Slide 06.08: Review: Thermometer - Slide - Video timestamp

• Slide 06.09: Review: Manometer - Slide - Video timestamp

• Slide 06.10: Review: Partial Pressures and Chemical Potentials - Slide - Video timestamp

• Slide 06.11: Review: Construction of the Fundamental Relation - Slide - Video timestamp

• Slide 06.13: Changing Variables by Means of Legendre Transform - Slide - Video timestamp

• Slide 06.14: Characteristic Functions from Legendre Transforms - Slide - Video timestamp

• Slide 06.15: Maxwell Relations; Helmholts and Gibbs Free Energy - Slide - Video timestamp

• Slide 06.16: Maxwell Relations; Partial Entropy and Volume - Slide - Video timestamp

• Slide 06.17: Other Characteristic Functions - Slide - Video timestamp

• Slide 06.18: Massieu, Hortsmann-Planck, and Euler Free Entropy - Slide - Video timestamp

• Slide 06.19: Availability Functions - Slide - Video timestamp

• Slide 06.20: Available Energy (Fixed Volume and Amounts) - Slide - Video timestamp

• Slide 06.22: Stability Conditions from Available Energy - Slide - Video timestamp

• Slide 06.25: LeChatelier-Braun Principle (Part I) - Slide - Video timestamp

FAQs for Lecture 06

Analytical Index of Lecture 6 Contents

• Availability function and related stability conditions - Slide - Video timestamp

• Availability function general concept - Slide - Video timestamp

• Availability function graphical representation - Slide - Video timestamp

• Availability function w.r.to a reservoir with fixed Volume and Amounts of Constituents - Slide - Video timestamp

• Available energy and its related availability function - Slide - Video timestamp

• Available energy graphical representation - Slide - Video timestamp

• Available energy w.r.to a reservoir with fixed Volume and Amounts of Constituents - Slide - Video timestamp

• Available energy w.r.to a reservoir variable Volume and fixed Amounts of Constituents - Slide - Video timestamp

• Characteristic Stable-Equilibrium-State functions - Slide - Video timestamp

• Characteristic Stable-Equilibrium-State functions - Slide - Video timestamp

• Enthalpy definition - Slide - Video timestamp

• Enthalpy of isothermobaric mixing - Slide - Video timestamp

• Euler free energy definition - Slide - Video timestamp

• Euler free entropy definition - Slide - Video timestamp

• Fundamental relation concavity - Slide - Video timestamp

• Fundamental relation construction from measurements - Slide - Video timestamp

• Gibbs free energy definition - Slide - Video timestamp

• Heat interaction definition - Slide - Video timestamp

• Heat interaction in a continuum - Slide - Video timestamp

• Helmholtz free energy - Slide - Video timestamp

• Hessian - Slide - Video timestamp

• Hessian - Slide - Video timestamp

• Hill, Terrell L. - Slide - Video timestamp

• Hortsmann free entropy - Slide - Video timestamp

• LeChatelier-Braun principle assertion I - Slide - Video timestamp

• Legendre transform of fundamental relation in energy form - Slide - Video timestamp

• Legendre transform of fundamental relation in entropy form - Slide - Video timestamp

• Massieu free entropy - Slide - Video timestamp

• Maxwell relations - Slide - Video timestamp

• Maxwell relations - Slide - Video timestamp

• Maxwell relations - Slide - Video timestamp

• Modes of interaction between systems Heat - Slide - Video timestamp

• Nanothermodynamics - Slide - Video timestamp

• Osmotic free energy definition - Slide - Video timestamp

• Partial pressure measurement - Slide - Video timestamp

• Planck free entropy - Slide - Video timestamp

• Pressure capturing tendency for energy - Slide - Video timestamp

• Pressure measurement - Slide - Video timestamp

• Small systems general comments on the range of validity of thermodynamics - Slide - Video timestamp

• Small systems much of thermodynamics still holds - Slide - Video timestamp

• Small systems properties of a pure substance - Slide - Video timestamp

• Small systems properties of mixtures - Slide - Video timestamp

• Stability conditions and availability functions - Slide - Video timestamp

• Stability conditions and availability functions - Slide - Video timestamp

• Stability conditions and LeChatelier-Braun principle - Slide - Video timestamp

• Stable equilibrium state properties of a pure substance (large number of particles) - Slide - Video timestamp

• Stable equilibrium state properties of a pure substance (small number of particles) - Slide - Video timestamp

• Stable equilibrium state properties of mixtures (large number of particles) - Slide - Video timestamp

• Stable equilibrium state properties of mixtures (small number of particles) - Slide - Video timestamp

• Temperature escaping tendency for energy - Slide - Video timestamp

• Temperature measurement - Slide - Video timestamp

• Thermal reservoir with fixed Volume and Amounts of Constituents - Slide - Video timestamp

• Thermal reservoir with variable Volume and Amounts of Constituents - Slide - Video timestamp

• Thermodynamics much of it applies also to modeling of small systems - Slide - Video timestamp

• Thermodynamics of small systems - Slide - Video timestamp

Back to the main course index page to see more lectures and direct links to the 2.43 MIT-OCW webpages.

See the Complete Analytical Index of the Course with Hyperlinks to All Videos and Slides.