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Table of Contents of Lecture 5

• Slide 05.01: Welcome - Slide - Video timestamp

• Slide 05.02: Review: a More Precise Clausius Inequality - Slide - Video timestamp

• Slide 05.03: Types of Interactions Between System - Slide - Video timestamp

• Slide 05.04: Definition of Work Interaction - Slide - Video timestamp

• Slide 05.05: Definition of Non-Work Interaction - Slide - Video timestamp

• Slide 05.06: Definition of Heat Interaction - Slide - Video timestamp

• Slide 05.07: Our Definition of Heat versus Heat Transfer - Slide - Video timestamp

• Slide 05.08: Steady State Heat Transfer Requires Nonequilibrium - Slide - Video timestamp

• Slide 05.11: Energy and Entropy Exchanges Between Reservoirs - Slide - Video timestamp

• Slide 05.12: Interposing a System Makes Reversibility Possible - Slide - Video timestamp

• Slide 05.13: Heat Engine Between Two Thermal Reservoirs - Slide - Video timestamp

• Slide 05.14: Refrigerator Between Two Thermal Reservoirs - Slide - Video timestamp

• Slide 05.15: Heat Pump Between Two Thermal Reservoirs - Slide - Video timestamp

• Slide 05.16: Measurements of Stable-Equilibrium Properties - Slide - Video timestamp

• Slide 05.17: Thermometer - Slide - Video timestamp

• Slide 05.18: Manometer - Slide - Video timestamp

• Slide 05.19: Pressure vs Force per Unit Area - Slide - Video timestamp

• Slide 05.20: Heat Capacities - Slide - Video timestamp

• Slide 05.21: Enthalpy and Heat Capacity at Constant Pressure - Slide - Video timestamp

• Slide 05.22: Heat Capacity at Constant Volume - Slide - Video timestamp

• Slide 05.23: Equation of State - Slide - Video timestamp

• Slide 05.24: Mayer Relation, Sound Speed, Etc - Slide - Video timestamp

• Slide 05.25: Gibbs Free Energy and Chemical Potentials - Slide - Video timestamp

• Slide 05.26: Partial Pressures and Chemical Potentials - Slide - Video timestamp

• Slide 05.27: Summary of Properties - Slide - Video timestamp

• Slide 05.28: Fundamental Relation from Measurements - Slide - Video timestamp

• Slide 05.30: Changing Variables by Means of Legendre Transform - Slide - Video timestamp

FAQs for Lecture 05

Analytical Index of Lecture 5 Contents

• Adiabatic process definition - Slide - Video timestamp

• Adiabatic process versus weight process - Slide - Video timestamp

• Carnot coefficient - Slide - Video timestamp

• Carnot coefficient - Slide - Video timestamp

• Chemical potential as functions of $T$ and $p$ - Slide - Video timestamp

• Clausius inequalities and irreversibilities - Slide - Video timestamp

• Clausius inequalities graphical proof - Slide - Video timestamp

• Clausius inequalities proof - Slide - Video timestamp

• Energy vs entropy diagram graphical proof of Clausius inequalities - Slide - Video timestamp

• Enthalpy definition - Slide - Video timestamp

• Equation of state - Slide - Video timestamp

• First-law efficiency for a heat engine - Slide - Video timestamp

• First-law efficiency for a heat pump - Slide - Video timestamp

• First-law efficiency for a refrigerator - Slide - Video timestamp

• Fundamental relation construction from measurements - Slide - Video timestamp

• Gibbs free energy definition - Slide - Video timestamp

• Heat capacity at costant pressure - Slide - Video timestamp

• Heat capacity at costant volume - Slide - Video timestamp

• Heat engines between reservoirs - Slide - Video timestamp

• Heat engines, heat pumps, refrigerators - Slide - Video timestamp

• Heat interaction definition - Slide - Video timestamp

• Heat interaction definition versus usual understanding - Slide - Video timestamp

• Heat interaction in a continuum - Slide - Video timestamp

• Heat transfer requires nonequilibrium - Slide - Video timestamp

• Isobaric expansion coefficient - Slide - Video timestamp

• Isoentropic compressibility - Slide - Video timestamp

• Isothermal compressibility - Slide - Video timestamp

• Joule coefficient - Slide - Video timestamp

• Joule-Thomson coefficient - Slide - Video timestamp

• Legendre transform definition - Slide - Video timestamp

• Local equilibrium assumption in heat transfer - Slide - Video timestamp

• Manometer - Slide - Video timestamp

• Mayer relation - Slide - Video timestamp

• Measurement procedure defining chemical potentials - Slide - Video timestamp

• Measurement procedure defining heat capacities - Slide - Video timestamp

• Measurement procedure defining partial pressures - Slide - Video timestamp

• Measurement procedure defining pressure - Slide - Video timestamp

• Measurement procedure defining temperature - Slide - Video timestamp

• Modes of interaction between systems Heat - Slide - Video timestamp

• Modes of interaction between systems Work - Slide - Video timestamp

• Non-work interaction definition - Slide - Video timestamp

• Non-work interaction not necessarily heat - Slide - Video timestamp

• Partial pressure definition - Slide - Video timestamp

• Pressure measurement - Slide - Video timestamp

• Pressure vs force per unit area - Slide - Video timestamp

• Second law of Thermodynamics proof of Clausius statement - Slide - Video timestamp

• Second-law efficiency for a heat engine - Slide - Video timestamp

• Second-law efficiency for a heat pump - Slide - Video timestamp

• Second-law efficiency for a refrigerator - Slide - Video timestamp

• Speed of sound propagation - Slide - Video timestamp

• Temperature measurement - Slide - Video timestamp

• Thermometer - Slide - Video timestamp

• Weight process versus adiabatic process - Slide - Video timestamp

• Work interaction, definition - Slide - Video timestamp

Back to the main course index page to see more lectures and direct links to the 2.43 MIT-OCW webpages.

See the Complete Analytical Index of the Course with Hyperlinks to All Videos and Slides.