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Table of Contents of Lecture 20

• Slide 20.01: Welcome - Slide - Video timestamp

• Slide 20.02: Activated Complex in the Simple System Model - Slide - Video timestamp

• Slide 20.03: Extension of the Simple System: Assumptions - Slide - Video timestamp

• Slide 20.05: Affinities and Non-Equilibrium Law of Mass Action - Slide - Video timestamp

• Slide 20.06: Self-Ionization of Pure Liquid Water: pH and pOH - Slide - Video timestamp

• Slide 20.07: Introduction to Chemical Kinetics - Slide - Video timestamp

• Slide 20.08: Potential Energy Surface and the Activated Complex - Slide - Video timestamp

• Slide 20.09: Maxwell-Boltzmann Distribution of Velocities - Slide - Video timestamp

• Slide 20.10: Arrhenius Activation Barrier - Slide - Video timestamp

• Slide 20.11: Reaction Rates and Collision Probabilities - Slide - Video timestamp

• Slide 20.12: Hydrocarbon Oxidation: Detailed Kinetic Mechanisms - Slide - Video timestamp

• Slide 20.13: Detailed Balance and Degree of Disequilibrium - Slide - Video timestamp

• Slide 20.14: Direction of Reaction and Fluctuation Relation - Slide - Video timestamp

• Slide 20.15: Half-Equilibrium of the Activated Complex - Slide - Video timestamp

• Slide 20.16: When Some Reactions Are Much Faster than Others - Slide - Video timestamp

• Slide 20.17: Nonequilibrium Build Up in Supersonic Nozzle - Slide - Video timestamp

• Slide 20.18: Degree of Disequilibrium Build Up in a Nozzle - Slide - Video timestamp

• Slide 20.19: Nonequilibrium Gasdynamic Infrared Power Laser - Slide - Video timestamp

• Slide 20.20: Vibrational Levels of the CO2 Molecule - Slide - Video timestamp

FAQs for Lecture 20

Analytical Index of Lecture 20 Contents

• Activated complex - Slide - Video timestamp

• Activated complex - Slide - Video timestamp

• Affinity and degree of disequilibrium - Slide - Video timestamp

• Affinity and direction of reaction - Slide - Video timestamp

• Affinity entropic versus energetic - Slide - Video timestamp

• Arrhenius law and activation barrier - Slide - Video timestamp

• Chemical equilibrium pH and pOH of pure water - Slide - Video timestamp

• Chemical kinetics - Slide - Video timestamp

• Coherent light - Slide - Video timestamp

• Collisions in reacting systems - Slide - Video timestamp

• Degree of disequilibrium in chemical kinetics - Slide - Video timestamp

• Degree of disequilibrium in chemical kinetics - Slide - Video timestamp

• Detailed balance principle - Slide - Video timestamp

• Equilibrium constant for pure water - Slide - Video timestamp

• Equilibrium constant in non-equilibrium law of mass action - Slide - Video timestamp

• Fluctuation relation in chemical kinetics - Slide - Video timestamp

• Forward and backward half-reactions - Slide - Video timestamp

• Inversion of population - Slide - Video timestamp

• Keck, James C. - Slide - Video timestamp

• Laser based on nonequilibrium buildup in a nozzle - Slide - Video timestamp

• Law of mass action for ideal Gibbs-Dalton gas mixtures - Slide - Video timestamp

• Maxwell-Boltzmann distribution of velocities - Slide - Video timestamp

• Nonequilibrium gasdynamic infrared power laser - Slide - Video timestamp

• Nonequilibrium law of mass action for ideal Gibbs-Dalton gas mixtures - Slide - Video timestamp

• Partial shifting chemical equilibrium - Slide - Video timestamp

• Potential energy surface - Slide - Video timestamp

• Principle of detailed balance - Slide - Video timestamp

• Reaction rate constants - Slide - Video timestamp

• Reaction rate constants - Slide - Video timestamp

• Reaction rates - Slide - Video timestamp

• Reaction rates - Slide - Video timestamp

• Simple-system model extension for reacting systems - Slide - Video timestamp

• Spontanueous emission of photons - Slide - Video timestamp

• Stimulated emission of photons - Slide - Video timestamp

• Thermal diffusivity - Slide - Video timestamp

• Vibrational levels of the CO2 molecule - Slide - Video timestamp

Back to the main course index page to see more lectures and direct links to the 2.43 MIT-OCW webpages.

See the Complete Analytical Index of the Course with Hyperlinks to All Videos and Slides.