Pair up the words so that the two words in each pair can be preceded or followed by the same word to make a longer word or two-word phrase. Then find a third word which also makes a word or phrase with the same preceding or following word. This is highly ambiguous, but if you do it correctly then each third word is used twice:
jumping \
lumber -JACK
BLACK <
night -GUARD
trigger /
/guitar
ELECTRIC-meter
\CIRCUIT \
ice -BREAKER
path /
/barrel
GUN-powder
\DOG \
rasp -BERRY
straw /
/pound
QUARTER-staff
>FINAL
SEMI-quaver
\skim
cayenne \
whole -PEPPER
GREEN <
kidney -BEAN
string /
/computer
MICRO-scope
>LIGHT
SUN-beam
\down
/machine
TIME-zone
\WASTE \
flash -PAPER
manila /
/potato
WHITE-wash
\WATER \
not -GATE
star /
Sort the third words alphabetically, concatenate them and extract the letters with the indices stated in the puzzle:
blaCKcirCuitdogfinAlgreenLightwastEwater
RASP/STRAW = BERRY LUMBER/JUMPING = JACK ==> BERRY/JACK = BLACK <== COMPUTER/POTATO = CHIP SKIM/WHOLE = MILK ==> CHIP/MILK = CHOCOLATE <== POUND/METER = UNIT OF MEASURE PATH/SCOPE = TELE ==> UNIT OF MEASURE/TELE = GRAM <== STRING/KIDNEY = BEAN MANILLA/CAYANNE = CAPITAL CITIES ==> BEAN/CAPITAL CITIES = LIMA <== ZONE/MACHINE = TIME TRIGGER/BARREL = GUN PARTS ==> TIME/GUN PARTS = MAGAZINE <== GUITAR/ICE = PICK NOT/NIGHT = WORDS THAT MAKE A HOMOPHONE WHEN YOU APPEND "K" ==> PICK/APPEND "K" = NIT <== WASH/POWDER = BATHROOM NAMES STAFF/QUAVER = MUSIC NOTATION ==> BATHROOM NAMES/MUSIC NOTATION = REST <== STAR/FLASH = LIGHT BEAM/DOWN = SUN ==> LIGHT/SUN = SPOT <==Words produced by this extraction and listed in a string alphabetically form: blaCKchoColategramLimamagAzinenitrEstspot. This also gives an anagram of CACKLE, which is the answer.